The Plastics Today for the Technologies of Tomorrow

Fluoroplastics for High-Performance Industrial Applications

Fluoroplastics are a class of paraffinic polymers that have some or all of the hydrogen replaced by fluorine. The fluoroplastic group in this catalog includes: FEP, fluorinated ethylene propylene; Kel-F, polychlorotrifluorethylene; PVDF, polyvinylidene fluoride; Rulon, forms of TFE fluorocarbon; TFE, virgin and mechanical, polytetrafluoroethylene; Tefzel, a modified copolymer of ethylene and tetrafluoroethylene; and Turcite.

The fluoroplastic group is characterized by excellent chemical resistance, excellent heat resistance, good electrical properties, and excellent wear resistance.

The chemical resistance of this group is unequaled by almost any other substance. Its virtual inertness to most chemicals make it an excellent choice for applications in corrosive environments. Fluoroplastics also retain their structural integrity at extremely high or low temperatures, i.e., +500 degrees F to (-110 degrees F) for Teflon. Because it absorbs little electrical energy, it excells as an electrical insulation material.

However, despite these attributes, perhaps the most desired characteristic of this group of plastics is their ability to resist abrasion. Simply stated, here is a chemist’s explanation for this unique property: A tightly bonded, impenetrible shield of fluorine atoms surrounds and protects an interior chain of carbon atoms. Unlike other materials, whose molecules lock into each other then break off when sliding takes place, these molecules have very little attraction for other substances. Result: No body takes place and there is an extremely low coefficient of friction.

Fluorocarbons may be filled or alloyed to enhance certain mechanical properties such as modular and strength. The desirable fluorocarbon properties of chemical and heat resistance are generally retained, but the price is, of course, greater for a filled fluoroplastic.

The unique chemical, electrical, thermal, and surface characterisitics make fluorocarbons ideally suited to a myriad of engineering uses which no other plastic has achieved. This group is available in a wide range of profiles, including: sheet, rod, tubing, and film.

Fluoroplastics
FEPKEL-FPFAPVDF
KYNAR
RULONTEFZELTFETURCITE
PHYSICAL
SPECIFIC GRAVITY2.12 – 2.172.08 – 2.1851.75 – 1.792.241.72.1 – 2.31.50
WATER ABSORPTION, 24 hr. (%)<0.010.000.000.00<0.03%0.00 – .005.06
MECHANICAL
TENSILE
Strength, Yield (10³ psi) @ 73°F3.0 – 4.05.73.65.0 – 7.0126.51.5 – 5.05.5
Elongation, Ultimate (%) @ 73°F30015030050 – 25010030075 – 35012
Modulus, Yield (10³ psi) @ 73°F207200 – 35050 – 90
FLEXURAL
Strength (10³ psi) @ 73°F8.56.6 – 16.0No break11.7
Modulus, Yield (10³ psi) @ 73°F9518090180 – 33714090 – 110
COMPRESSIVE STRENGTH
2% Offset (10³ psi)5.5
IMPACT STRENGTH
Izod, Notched (ft-lb/in.) @ 73°FNo break5.0 D553.0 – 6.0 D76-806.0 D60-75R10-20D75
HARDNESS
COEFFICIENT OF STATIC FRICTION
Against steel14 – 170.4 – 1.0
Against itself
THERMAL
CONDUCTIVITY
(BTU/hr/sq ft/°F/in.)
1.07.0 – .872.3
COEFFICIENT OF THERMAL EXPANSION
(10⁻⁶/°F)
3.995.46.6145.5 – 7.55.5
SPECIFIC HEAT
(BTU/lb/°F)
0.21530 – 34
HEAT DEFLECTION TEMP (°F)
At 66 psi158258257 – 284100 – 140
At 264 psi167188 – 239
MAX. CONTINUOUS TEMP (°F)400380300550500160
ELECTRICAL
VOLUME RESISTIVITY
(Ohm-cm)
>10¹⁶1.2 × 10¹⁴5 × 10¹⁴1 × 10¹⁵>10¹⁷
DIELECTRIC STRENGTH
(V/mil)
21005004000/5000260 – 12807000500 – 650
DIELECTRIC CONSTANT
At 60 Hz2.13.02.0610.02.62.0 – 2.1
At 1 MHz2.12.52.067.52.62.0 – 2.1
DISSIPATION FACTOR
At 60 Hz0.0020.0050.0500.004
At 1 MHz0.0070.0070.184
ARC RESISTANCE (SECONDS)300360300180 – 240